Le pubblicazioni scientifiche dei Professori Sergio Brovelli e Francesco Meinardi su Nature
Highly efficient luminescent solar concentrators based on earth-abundant indirect-bandgap silicon quantum dots, Nature Photonics 20-02-2017
Building-integrated photovoltaics is gaining consensus as a renewable energy technology for producing electricity at the point of use. Luminescent solar concentrators (LSCs) could extend architectural integration to the urban environment by realizing electrode-less photovoltaic windows. Crucial for large-area LSCs is the suppression of reabsorption losses, which requires emitters with negligible overlap between their absorption and emission spectra. Here, we demonstrate the use of indirect-bandgap semiconductor nanostructures such as highly emissive silicon quantum dots. Silicon is non-toxic, low-cost and ultra-earth-abundant, which avoids the limitations to the industrial scaling of quantum dots composed of low-abundance elements. Suppressed reabsorption and scattering losses lead to nearly ideal LSCs with an optical efficiency of η = 2.85%, matching state-of-the-art semi-transparent LSCs. Monte Carlo simulations indicate that optimized silicon quantum dot LSCs have a clear path to η > 5% for 1 m2 devices. We are finally able to realize flexible LSCs with performances comparable to those of flat concentrators, which opens the way to a new design freedom for building-integrated photovoltaics elements.
Highly efficient large-area colourless luminescent solar concentrators using heavy-metal-free colloidal quantum dots, Nature Nanotechnology 24-08-2015
Luminescent solar concentrators serving as semitransparent photovoltaic windows could become an important element in net zero energy consumption buildings of the future. Colloidal quantum dots are promising materials for luminescent solar concentrators as they can be engineered to provide the large Stokes shift necessary for suppressing reabsorption losses in large-area devices. Existing Stokes-shift-engineered quantum dots allow for only partial coverage of the solar spectrum, which limits their light-harvesting ability and leads to colouring of the luminescent solar concentrators, complicating their use in architecture. Here, we use quantum dots of ternary I–III–VI2 semiconductors to realize the first large-area quantum dot–luminescent solar concentrators free of toxic elements, with reduced reabsorption and extended coverage of the solar spectrum. By incorporating CuInSexS2–x quantum dots into photo-polymerized poly(lauryl methacrylate), we obtain freestanding, colourless slabs that introduce no distortion to perceived colours and are thus well suited for the realization of photovoltaic windows. Thanks to the suppressed reabsorption and high emission efficiencies of the quantum dots, we achieve an optical power efficiency of 3.2%. Ultrafast spectroscopy studies suggest that the Stokes-shifted emission involves a conduction-band electron and a hole residing in an intragap state associated with a native defect.
Large-area luminescent solar concentrators based on ‘Stokes-shift-engineered’ nanocrystals in a mass-polymerized PMMA matrix, Nature Photonics 13-04-2014
Luminescent solar concentrators are cost-effective complements to semiconductor photovoltaics that can boost the output of solar cells and allow for the integration of photovoltaic-active architectural elements into buildings (for example, photovoltaic windows). Colloidal quantum dots are attractive for use in luminescent solar concentrators, but their small Stokes shift results in reabsorption losses that hinder the realization of large-area devices. Here, we use ‘Stokes-shift-engineered’ CdSe/CdS quantum dots with giant shells (giant quantum dots) to realize luminescent solar concentrators without reabsorption losses for device dimensions up to tens of centimetres. Monte-Carlo simulations show a 100-fold increase in efficiency using giant quantum dots compared with core-only nanocrystals. We demonstrate the feasibility of this approach by using high-optical-quality quantum dot–polymethylmethacrylate nanocomposites fabricated using a modified industrial method that preserves the light-emitting properties of giant quantum dots upon incorporation into the polymer. Study of these luminescent solar concentrators yields optical efficiencies >10% and an effective concentration factor of 4.4. These results demonstrate the significant promise of Stokes-shift-engineered quantum dots for large-area luminescent solar concentrators.
Doped Halide Perovskite Nanocrystals for Reabsorption-Free Luminescent Solar Concentrators, ACS Energy Letters 15-09-2017
Halide perovskite nanocrystals (NCs) are promising solution-processed emitters for low-cost optoelectronics and photonics. Doping adds a degree of freedom for their design and enables us to fully decouple their absorption and emission functions. This is paramount for luminescent solar concentrators (LSCs) that enable fabrication of electrode-less solar windows for building-integrated photovoltaic applications. Here, we demonstrate the suitability of manganese-doped CsPbCl3 NCs as reabsorption-free emitters for large-area LSCs. Light propagation measurements and Monte Carlo simulations indicate that the dopant emission is unaffected by reabsorption. Nanocomposite LSCs were fabricated via mass copolymerization of acrylate monomers, ensuring thermal and mechanical stability and optimal compatibility of the NCs, with fully preserved emission efficiency. As a result, perovskite LSCs behave closely to ideal devices, in which all portions of the illuminated area contribute equally to the total optical power. These results demonstrate the potential of doped perovskite NCs for LSCs, as well as for other photonic technologies relying on low-attenuation long-range optical wave guiding.